Zirconium and Titanium Mediated Hydroboration of Alkenes and Alkynes
نویسندگان
چکیده
منابع مشابه
Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes.
The highly chemo-, regio-, and stereoselective synthesis of alkyl- and vinyl boronic esters with good functional group tolerance has been developed using in situ activation of a bench-stable iron(II) pre-catalyst and pinacolborane (16 examples, 45-95% yield, TOF up to 30,000 mol h(-1)). The first iron-catalysed alkene hydrogermylation is also reported.
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ژورنال
عنوان ژورنال: Chinese Journal of Organic Chemistry
سال: 2023
ISSN: ['0253-2786']
DOI: https://doi.org/10.6023/cjoc202212022